وقائع مؤتمر -
Diffusion and ion carrier mobility studies in binary SPEs based on PVA integrated with K+ ion provider salt: structural and electrical insights
وقائع مؤتمر -
Diffusion and ion carrier mobility studies in binary SPEs based on PVA integrated with K+ ion provider salt: structural and electrical insights
[[TEST]] This Field is filled to bypass the test process of the Thirdmission platform
Acknowledgements
The authors gratefully acknowledge the support for this study from the Ministry of Higher Education and Scientific Research-Kurdistan Regional Government, Department of Physics, College of Science, University of Sulaimani, Sulaimani 46001, Kurdistan Regional Government/Iraq.
Ion dissociation in polymer electrolytes is the subject of intensive debate. The current work is an attempt to understand ion transport parameters associated with K+ ion dynamics. The amorphous phases depicted from the XRD pattern and found to increase with increasing salt concentration. The SCN− bands from FTIR spectra were used to determine the free ion concentrations. The fitted impedance plots were used to determine the DC conductivity. From the impedance and FTIR approaches, the highest conductivity has achieved an optimum value of 5.71 × 10−6 S/cm for 40 wt.% of KSCN salt. In ε″ and ε′ spectra, dispersions were observed at low frequency due to the electrode polarization (EP) effect. The viscoelastic relaxation processes of K+ ions confirmed a coupling between ionic motion and polymer segmental movement. Based on the frequency exponent (s) value obtained from AC conductivity, the coulombic interactions among the ions and their effects on DC value are discussed.
معلومات الاقتباس
Zhou M, Bai P, Ji X, Yang J, Wang C, Xu Y (2021) Electrolytes and interphases in potassium ion batteries. Adv Mater 2003741(7):1–22. https://doi.org/10.1002/adma.202003741
Article
CAS
Google Scholar
Manjunath A, Deepa T, Supreetha NK, Irfan M (2015) Studies on AC electrical conductivity and dielectric properties of PVA / NH 4 NO 3 solid polymer electrolyte films. Adv Mater Phys Chem 5(3):295–301. https://doi.org/10.4236/ampc.2015.58029
Article
CAS
Google Scholar
Pantaloni S, Passerini S, Scrosati B (1987) Solid-state thermoelectrochromic display. Electrochem Soc 134:3
Article
Google Scholar
Armand MB (1986) Polymer electrolytes. Ann Rev Mater Sci 16:241–261
Article
Google Scholar
Ahmad H, Ikmar M, Mohamad N (2015) Conduction mechanism of solid biopolymer electrolytes system based on carboxymethyl cellulose – ammonium chloride. Am J Sustain Agric 9(2):1–7
Google Scholar
Masoud EM (2015) Citrated porous gel copolymer electrolyte composite for lithium ion batteries application : an investigation of ionic conduction in an optimized crystalline and porous structure. J Alloys Compd 651:157–163. https://doi.org/10.1016/j.jallcom.2015.08.079
Article
CAS
Google Scholar
Webb MA et al (2015) Systematic computational and experimental investigation of lithium-ion transport mechanisms in polyester-based polymer electrolytes. Am Chem Soc 1(4):198–205. https://doi.org/10.1021/acscentsci.5b00195
Article
CAS
Google Scholar
Subba CV, Ravi RM (2012) Preparation and characterization of PVP-based polymer electrolytes for solid-state battery applications. Iran Polym J 21:531–536. https://doi.org/10.1007/s13726-012-0058-6
Article
CAS
Google Scholar
Masoud EM (2019) Montmorillonite incorporated polymethylmethacrylate matrix containing lithium trifluoromethanesulphonate ( LTF ) salt : thermally stable polymer nanocomposite electrolyte for lithium- … Montmorillonite incorporated polymethylmethacrylate matrix containi. Ionics (Kiel) 25:2645–2656. https://doi.org/10.1007/s11581-018-2802-1
Article
CAS
Google Scholar
Hema M, Selvasekarapandian S, Hirankumar G, Sakunthala A, Arunkumar D, Nithya H (2010) “Laser Raman and ac impedance spectroscopic studies of PVA : NH 4 NO 3 polymer electrolyte”, Spectrochim. Acta Part A Mol Biomol Spectrosc 75:474–478. https://doi.org/10.1016/j.saa.2009.11.012
Article
CAS
Google Scholar
Kadir MFZ, Aspanut Z, Yahya R, Arof AK (2011) Chitosan – PEO proton conducting polymer electrolyte membrane doped with NH 4 NO 3. Mater Res Innov 15(3):s164–s167. https://doi.org/10.1179/143307511X13031890748812
Article
Google Scholar
Search H, Journals C, Contact A, Iopscience M, Address IP (2014) Conductivity and electrical properties of corn starch – chitosan blend biopolymer electrolyte incorporated with ammonium iodide. Phys Scr 89(3):035701. https://doi.org/10.1088/0031-8949/89/03/035701
Article
CAS
Google Scholar
Taylor P, Aziz NAN, Idris NK, Isa MIN (2010) Solid polymer electrolytes based on methylcellulose: FT-IR and ionic conductivity studies. Int J Polym Anal Charact 15(5):319–327. https://doi.org/10.1080/1023666X.2010.493291
Article
CAS
Google Scholar
Hirankumar G, Selvasekarapandian S, Kuwata N, Kawamura J, Hattori T (2005) Thermal, electrical and optical studies on the poly ( vinyl alcohol ) based polymer electrolytes. J Power Sources 144:262–267. https://doi.org/10.1016/j.jpowsour.2004.12.019
Article
CAS
Google Scholar
Reddy CVS, Jin A, Zhu Q, Mai L, Chen W (2006) Preparation and characterization of ( PVP + NaClO 4) electrolytes for battery applications. Eur Phys J E 476:471–476. https://doi.org/10.1140/epje/i2005-10076-8
Article
CAS
Google Scholar
Y Liu, C Gao, L Dai, Q Deng, L Wang, and J Luo, 2020 “The features and progress of electrolyte for potassium ion batteries,” small J., 16, 44, 1–13, https://doi.org/10.1002/smll.202004096.
Aziz SB, Abdullah OGH, Hussein SA (2018) Role of silver salts lattice energy on conductivity drops in chitosan based solid electrolyte : structural, morphological and electrical characteristics. J Electron Mater 47:3800–3808. https://doi.org/10.1007/s11664-018-6250-5
Article
CAS
Google Scholar
Aziz SB, Abdullah OG, Rasheed MA (2017) Structural and electrical characteristics of PVA:NaTf based solid polymer electrolytes: role of lattice energy of salts on electrical DC conductivity. J Mater Sci Mater Electron 28:12873–12884. https://doi.org/10.1007/s10854-017-7117-x
Article
CAS
Google Scholar
Yoder C (2016) Geochemical applications of the simple salt approximation to the lattice energies of complex materials geochemical applications of the simple salt approximation to the lattice energies of. Am Mineral 90:488–496. https://doi.org/10.2138/am.2005.1537
Article
CAS
Google Scholar
Pan Q, Gong D, Tang Y (2020) Recent progress and perspective on electrolytes for sodium/potassium-based devices. Energy Storage Mater 31:328–343. https://doi.org/10.1016/j.ensm.2020.06.025
Article
Google Scholar
Hirankumar G, Selvasekarapandian S, Bhuvaneswari MS, Baskaran R, Vijayakumar M (2006) Ag + ion transport studies in a polyvinyl alcohol-based polymer electrolyte system. J Solid State Electrochem 10:193–197. https://doi.org/10.1007/s10008-004-0612-z
Article
CAS
Google Scholar
Mazuki NF, Majeed APPA, Nagao Y, Samsudin AS (2020) Studies on ionics conduction properties of modification CMC-PVA based polymer blend electrolytes via impedance approach. Polym Test 81:106234. https://doi.org/10.1016/j.polymertesting.2019.106234
Article
CAS
Google Scholar
Roth WL (1972) Ionic transport in super ionic conductors : a theoretical model. J Solid State Chem 4(2):294–310
Article
Google Scholar
Bandara TMWJ, Dissanayake MAKL, Albinsson I, Mellander B (2011) Mobile charge carrier concentration and mobility of a polymer electrolyte containing PEO and Pr 4 N + I − using electrical and dielectric measurements. Solid State Ionics 189(1):63–68. https://doi.org/10.1016/j.ssi.2011.03.004
Article
CAS
Google Scholar
Arof AK (2013) A method based on impedance spectroscopy to determine transport properties of polymer electrolytes. Phys Chem Chem Phys 14:1856. https://doi.org/10.1039/c3cp53830c
Article
CAS
Google Scholar
Bhargav PB, Mohan VM, Sharma AK, Rao VVRN (2009) Investigations on electrical properties of ( PVA : NaF ) polymer electrolytes for electrochemical cell applications. Curr Appl Phys 9:165–171. https://doi.org/10.1016/j.cap.2008.01.006
Article
Google Scholar
Golodnitsky D, Livshits E, Rosenberg Y, Peled E, Chung SH (2000) A new approach to the understanding of ion transport in semicrystalline polymer electrolytes. J Electroanal Chem 491:203–210
Article
CAS
Google Scholar
Gh O, Aziz SB, Rasheed MA (2016) Structural and optical characterization of PVA:KMnO4 based solid polymer electrolyte. Results Phys 6:1103–1108. https://doi.org/10.1016/j.rinp.2016.11.050
Article
Google Scholar
Aziz SB, Abidin ZHZ (2015) Ion-transport study in nanocomposite solid polymer electrolytes based on chitosan : electrical and dielectric analysis. J Appl Polym Sci 132(15):1–10. https://doi.org/10.1002/app.41774
Article
CAS
Google Scholar
Aziz SB, Abidin ZHZ (2013) Electrical conduction mechanism in solid polymer electrolytes : new concepts to arrhenius equation. J Soft Matter 2013:8
Article
Google Scholar
Aziz SB, Kadir MFZ, Abidin ZHZ (2016) Structural, morphological and electrochemical impedance study of CS : LiTf based solid polymer electrolyte : reformulated arrhenius equation for ion transport study. Int J Electrochem Sci 11:9228–9244. https://doi.org/10.20964/2016.11.18
Article
CAS
Google Scholar
Bdewi SF, Gh O, Bakhtyar A, Ayad KA (2015) Synthesis, structural and optical characterization of MgO nanocrystalline embedded in PVA matrix. J Inorg Organomet Polym Mater 26:326–334. https://doi.org/10.1007/s10904-015-0321-3
Article
CAS
Google Scholar
Chandrakala HN, Ramaraj B, Madhu GM (2012) Shivakumaraiah, and Siddaramaiah, “The influence of zinc oxide – cerium oxide nanoparticles on the structural characteristics and electrical properties of polyvinyl alcohol films.” J Mater Sci 47:8076–8084. https://doi.org/10.1007/s10853-012-6701-y
Article
CAS
Google Scholar
Shamsuri NA, Zaine SNA, Yusof YM, Yahya WZN, Shukur MF (2020) Effect of ammonium thiocyanate on ionic conductivity and thermal properties of polyvinyl alcohol – methylcellulose – based polymer electrolytes. Ionics (Kiel) 26:6083–6093
Article
CAS
Google Scholar
Nofal MM, Karim WO, Asnawi ASFM, Hadi JM, Fakhrul M, Abdul Z (2021) A polymer blend electrolyte based on CS with enhanced ion transport and electrochemical properties for electrical double layer capacitor applications. Polymers (Basel) 13(6):930
Article
CAS
Google Scholar
Woo HJ, Majid SR, Arof AK (2011) Conduction and thermal properties of a proton conducting polymer electrolyte based on poly ( ε -caprolactone ). Solid State Ionics 199–200:14–20. https://doi.org/10.1016/j.ssi.2011.07.007
Article
CAS
Google Scholar
Hamsan MH, Shukur MF, Kadir MFZ (2017) NH 4 NO 3 as charge carrier contributor in glycerolized potato starch-methyl cellulose blend-based polymer electrolyte and the application in electrochemical double-layer capacitor. Ionics (Kiel) 23:3429–3453. https://doi.org/10.1007/s11581-017-2155-1
Article
CAS
Google Scholar
Jothi MA, Vanitha D (2021) Investigations of biodegradable polymer blend electrolytes based on cornstarch : PVP : NH 4 Cl and its potential application in solid-state batteries. J Mater Sci Mater Electron 32(5):5427–5441. https://doi.org/10.1007/s10854-021-05266-1
Article
CAS
Google Scholar
Noor NAM, Isa MIN (2019) Investigation on transport and thermal studies of solid polymer electrolyte based on carboxymethyl cellulose doped ammonium thiocyanate for potential application in electrochemical devices. Int J Hydrogen Energy 44(16):8298–8306. https://doi.org/10.1016/j.ijhydene.2019.02.062
Article
CAS
Google Scholar
Zulkifli A, Saadiah MA, Mazuki NF, Samsudin AS (2020) Characterization of an amorphous materials hybrid polymer electrolyte based on a LiNO3-doped, CMC-PVA blend for application in an electrical double layer capacitor. Mater Chem Phys 253:123312. https://doi.org/10.1016/j.matchemphys.2020.123312
Article
CAS
Google Scholar
Brza MA et al (2021) Characteristics of a plasticized PVA-based polymer electrolyte membrane and H + conductor for an electrical double-layer capacitor : structural, morphological, and ion transport properties. Membranes (Basel) 11(4):296
Article
CAS
Google Scholar
Ali NI, Zaharuddin SN, Syarmeen NA (2021) Conductivity and morphological studies of poly ( vinyl alcohol ) -magnesium triflate-ethylene carbonate gel polymer electrolyte. Sci Res J 18(2):161–175
Article
Google Scholar
Asnawi ASFM et al (2021) The study of plasticized sodium ion conducting polymer blend electrolyte membranes based on chitosan / dextran potential stability. Polymers (Basel) 13(3):383
Article
CAS
Google Scholar
Marf AS, Abdullah RM, Aziz SB (2020) Structural, morphological, electrical and electrochemical properties of PVA : CS-based proton-conducting polymer blend electrolytes. Membranes (Basel) 10(4):71
Article
CAS
Google Scholar
Al-muntaser AA, Abdelghany AM, Abdelrazek EM, Elshahawy AG (2019) Enhancement of optical and electrical properties of PVC / PMMA blend films doped with Li 4 Ti 5 O 12 nanoparticles. J Mater Res Technol 9(1):789–797. https://doi.org/10.1016/j.jmrt.2019.11.019
Article
CAS
Google Scholar
Pradhan DK, Naresh R, Choudhary P (2008) Studies of dielectric relaxation and AC conductivity behavior of plasticized polymer nanocomposite electrolytes. Int J Electrochem Sci 3:597–608
CAS
Google Scholar
Abdulwahid RT et al (2021) chitosan : dextran : impedance, dielectric properties, and energy storage study J Mater Sci : mater electron electrochemical performance of polymer blend electrolytes based on chitosan : dextran : impedance, dielectric properties, and energy storage s. J Mater Sci Mater Electron 32:14846–14862. https://doi.org/10.1007/s10854-021-06038-7
Article
CAS
Google Scholar
Asnawi ASFM et al (2020) Glycerolized Li + ion conducting chitosan-based polymer electrolyte for energy storage EDLC device applications with relatively high energy density. Polymers (Basel) 12(6):1433
Article
CAS
Google Scholar
Aziz SB et al (2020) Compatible solid polymer electrolyte based on methyl cellulose for energy storage application: structural, electrical, and electrochemical properties. Polymers (Basel) 12(10):2257
Article
CAS
Google Scholar
Das S, Ghosh A (2016) “Ionic conductivity and dielectric permittivity of polymer electrolyte plasticized with polyethylene glycol. AIP Conf Proc 1731:110012. https://doi.org/10.1063/1.4948033
Article
Google Scholar
Aziz SB (2015) Study of electrical percolation phenomenon from the dielectric. Bull Mater Sci 38:1597–1602. https://doi.org/10.1007/s12034-015-0978-9
Article
CAS
Google Scholar
Kulshrestha N, Chatterjee B, Gupta PN (2014) Structural, thermal, electrical, and dielectric properties of synthesized nanocomposite solid polymer electrolytes. High Perform Polym 26(6):677–688. https://doi.org/10.1177/0954008314541820
Article
CAS
Google Scholar
Aziz SB, Marif RB, Brza MA, Hamsan MH, Kadir MFZ (2019) Employing of Trukhan model to estimate ion transport parameters in PVA based solid polymer electrolyte. Polymers (Basel) 11(10):1694. https://doi.org/10.3390/polym11101694
Article
CAS
Google Scholar
Singh M, Singh VK, Surana K, Bhattacharya B, Singh PK, Rhee H (2013) Journal of industrial and engineering chemistry new polymer electrolyte for electrochemical application. J Ind Eng Chem 19(3):819–822. https://doi.org/10.1016/j.jiec.2012.10.023
Article
CAS
Google Scholar
Aziz SB, Hazrin Z, Abidin Z (2014) Electrical and morphological analysis of chitosan : AgTf solid electrolyte. Mater Chem Phys 144(3):280–286. https://doi.org/10.1016/j.matchemphys.2013.12.029
Article
CAS
Google Scholar
Hadi JM et al (2020) Electrochemical impedance study of proton conducting polymer electrolytes based on PVC doped with thiocyanate and plasticized with glycerol. Int J Electrochem Sci 15:4671–4683. https://doi.org/10.20964/2020.05.34
Article
CAS
Google Scholar
SB Aziz, MH Hamsan, MFZ Kadir, and HJ Woo, 2020 “Design of polymer blends based on chitosan : POZ with improved dielectric constant for application in polymer electrolytes and flexible electronics,” Adv. Polym. Technol., 2020,
Aziz SB, Mamand SM (2018) “The study of dielectric properties and conductivity relaxation of ion conducting chitosan. NaTf based solid electrolyte. 13:10274–10275. https://doi.org/10.20964/2018.11.05
Article
CAS
Google Scholar
Louati NAPOB, Hlel F, Guidara K (2009) Ac electrical properties and dielectric relaxation of the new mixed crystal (Na0.8Ag0.2)2PbP2O7. J. Alloys Compd. 486:299–303. https://doi.org/10.1016/j.jallcom.2009.06.148
Article
CAS
Google Scholar
Elkholy MM, El-Deen LMS (2000) The dielectric properties of TeO2 – P2O5 glasses. Mater Chem Phys 65:192–196
Article
CAS
Google Scholar
Anantha PS, Hariharan K (2005) ac conductivity analysis and dielectric relaxation behaviour of NaNO 3 – Al 2 O 3 composites. Mater Sci Eng 121:12–19. https://doi.org/10.1016/j.mseb.2004.12.005
Article
CAS
Google Scholar
Marzantowicz M, Dygas JR (2007) Conductivity and dielectric properties of polymer electrolytes PEO : LiN ( CF 3 SO 2) 2 near glass transition. J Non Cryst Solids 353:4467–4473. https://doi.org/10.1016/j.jnoncrysol.2007.04.046
Article
CAS
Google Scholar
Di Noto V, Vittadello M (2002) Mechanism of ionic conductivity in poly ( ethylene glycol 400)/ ( MgCl 2) x polymer electrolytes : studies based on electrical spectroscopy. Solid State Ionics 147:309–316
Article
Google Scholar
Aziz SB, Mamand SM (2018) The study of dielectric properties and conductivity relaxation of ion conducting chitosan : NaTf based solid electrolyte. Int J Electrochem Sci 13:10274–10288. https://doi.org/10.20964/2018.11.05
Article
CAS
Google Scholar
Aziz SB, Abdullah RM, Rasheed MA, Ahmed HM (2017) Role of ion dissociation on DC conductivity and silver nanoparticle formation in PVA : AgNt based polymer electrolytes : deep insights to ion. Polymers (Basel) 9(8):338. https://doi.org/10.3390/polym9080338
Article
PubMed Central
CAS
Google Scholar
Hassib H, Razik AA (2008) Dielectric properties and AC conduction mechanism for 5, 7-dihydroxy-6-formyl-2-methylbenzo-pyran-4-one bis-schiff base. Solid State Commun 147:345–349. https://doi.org/10.1016/j.ssc.2008.06.034
Article
CAS
Google Scholar
Sahoo PS, Panigrahi A, Patri SK, Choudhary RNP (2010) Impedance spectroscopy of Ba 3 Sr 2 DyTi 3 V 7 O 30 ceramic. Bull Mater Sci 33(2):129–134
Article
CAS
Google Scholar
Natesan B, Karan NK, Katiyar RS (2006) Ion relaxation dynamics and nearly constant loss behavior in polymer electrolyte. Phys. Rev. E 74:4. https://doi.org/10.1103/PhysRevE.74.042801
Article
CAS
Google Scholar
Yang J (2008) Hopping conduction and low-frequency dielectric relaxation in 5 mol % Mn doped ( Pb, Sr ) TiO3 films hopping conduction and low-frequency dielectric relaxation in 5mol % Mn doped ( Pb, Sr ) TiO3 films. J Appl Phys 104:104113. https://doi.org/10.1063/1.3021447
Article
CAS
Google Scholar
Migahed MD, Ishra M, Fahmy T, Barakat A (2004) Electric modulus and AC conductivity studies in conducting PPy composite films at low temperature Electric modulus and AC conductivity studies in conducting PPy composite films at low temperature. J Phys Chem Solids 65:1121–1125. https://doi.org/10.1016/j.jpcs.2003.11.039
Article
CAS
Google Scholar
Bhadra S, Singha NK, Khastgir D (2009) Dielectric properties and EMI shielding efficiency of polyaniline and ethylene 1-octene based semi-conducting composites. Curr Appl Phys 9(2):396–403. https://doi.org/10.1016/j.cap.2008.03.009
Article
Google Scholar
FK and HR, 1990. “Jump-relaxation model yields Kohlrausch-Williams-Watts behaviour,” Solid State Ionics, 40/41, 1, 200–204
Ravi M, Pavani Y, Kumar KK, Bhavani S, Sharma AK, Rao VVRN (2011) Studies on electrical and dielectric properties of PVP : KBrO 4 complexed polymer electrolyte films. Mater Chem Phys 130(1–2):442–448. https://doi.org/10.1016/j.matchemphys.2011.07.006
Article
CAS
Google Scholar
Mishra R, Baskaran N, Ramakrishnan PA, Rao KJ (1998) Lithium ion conduction in extreme polymer in salt regime. Solid State Ionics 112:261–273