Conference Proceeding Paper -

Diffusion and ion carrier mobility studies in binary SPEs based on PVA integrated with K+ ion provider salt: structural and electrical insights
Diffusion and ion carrier mobility studies in binary SPEs based on PVA integrated with K+ ion provider salt: structural and electrical insights

Conference Proceeding Paper -

Diffusion and ion carrier mobility studies in binary SPEs based on PVA integrated with K+ ion provider salt: structural and electrical insights

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Acknowledgements

The authors gratefully acknowledge the support for this study from the Ministry of Higher Education and Scientific Research-Kurdistan Regional Government, Department of Physics, College of Science, University of Sulaimani, Sulaimani 46001, Kurdistan Regional Government/Iraq.

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Ion dissociation in polymer electrolytes is the subject of intensive debate. The current work is an attempt to understand ion transport parameters associated with K+ ion dynamics. The amorphous phases depicted from the XRD pattern and found to increase with increasing salt concentration. The SCN− bands from FTIR spectra were used to determine the free ion concentrations. The fitted impedance plots were used to determine the DC conductivity. From the impedance and FTIR approaches, the highest conductivity has achieved an optimum value of 5.71 × 10−6 S/cm for 40 wt.% of KSCN salt. In ε″ and ε′ spectra, dispersions were observed at low frequency due to the electrode polarization (EP) effect. The viscoelastic relaxation processes of K+ ions confirmed a coupling between ionic motion and polymer segmental movement. Based on the frequency exponent (s) value obtained from AC conductivity, the coulombic interactions among the ions and their effects on DC value are discussed.

Citation Information

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